LOCAL COMPOSITION MODEL FOR EXCESS GIBBS ENERGY OF ELECTROLYTE SYSTEMS .1. SINGLE SOLVENT, SINGLE COMPLETELY DISSOCIATED ELECTROLYTE SYSTEMS
LOCAL COMPOSITION MODEL FOR EXCESS GIBBS ENERGY OF ELECTROLYTE SYSTEMS .1. SINGLE SOLVENT, SINGLE COMPLETELY DISSOCIATED ELECTROLYTE SYSTEMS
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DOI：
10.1002/aic.690280410
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发表时间：
1982-01-01
期刊：
影响因子：
3.7
通讯作者：
EVANS, LB
中科院分区：
文献类型：
--
作者：
CHEN, CC;BRITT, HI;EVANS, LB
针对过量吉布斯能量开发了电解质局域成分模型，假定吉布斯能量是两种贡献的总和，一种是由离子之间的长程静电力产生的，另一种是由所有物质之间的短程力产生的。该模型的有效性在涵盖从分子液体到熔盐的整个范围的系统中得到了证明。
An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.