Studies of gas absorption: II. Application of the liquid film resistance relationship to the absorption of carbon dioxide by solutions of diethanolamine
Studies of gas absorption: II. Application of the liquid film resistance relationship to the absorption of carbon dioxide by solutions of diethanolamine
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气体吸收的研究：II。
DOI：
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发表时间：
2010
期刊：
影响因子：
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通讯作者：
P. J. Hoftijzer
中科院分区：
文献类型：
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作者：
D. V. Krevelen;P. J. Hoftijzer
我们在前一篇文章1）中导出的洗涤器中液膜阻力对气体吸收的一般方程，被应用于Cryder和Maloney 2）的实验，处理二乙醇胺溶液中二氧化碳的吸收。当假定反应为伪三级反应时，我们的方程也被证明是有效的。实际上，它将是连续的两个二级反应，因为没有发现温度对反应速度常数的影响。
The general equation for liquid film resistance to gas absorption in scrubbers, derived by us in a previous paper 1), was applied to experiments of Cryder and Maloney2), treating the absorption of carbon dioxide in diethanolamine solutions. Our equation proved to be valid also in this case, when it is assumed that the reaction is a pseudo-third order reaction. In reality it will be a succession of two second order reactions, as no temperature influence on the reaction velocity constant is found.