A view on systematic truncation of tetrahedral ligands for coordination polymers
A view on systematic truncation of tetrahedral ligands for coordination polymers
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DOI：
10.1039/c6ce02384c
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发表时间：
2017-01
期刊：
影响因子：
3.1
通讯作者：
Tian Zhao;C. Heering;I. Boldog;K. V. Domasevitch;C. Janiak
中科院分区：
文献类型：
--
作者：
Tian Zhao;C. Heering;I. Boldog;K. V. Domasevitch;C. Janiak
二，三，四（羧基苯基）金刚烷的配合物的d-金属的配合物的合成进行了探索，与Mn，Co，和Cd的成功结果。基于小团簇的sql、hcb和dia框架的形成证明了配体形状在定义结晶结果中的主导作用。
Bis-, tris- and tetrakis(carboxyphenyl)adamantanes were probed for the synthesis of coordination polymers of d-metals, with a successful outcome for Mn, Co, and Cd. Formation of sql, hcb and dia frameworks based on small clusters demonstrates the dominant role of the ligand shape in defining the outcome of crystallization.