Dinitrogen Activation and Addition to Unsaturated C-E (E=C, N, O, S) Bonds Mediated by Transition Metal Complexes
Dinitrogen Activation and Addition to Unsaturated C-E (E=C, N, O, S) Bonds Mediated by Transition Metal Complexes
复制标题
过渡金属配合物介导的二氮活化和不饱和 C-E (E=C, N, O, S) 键加成
DOI：
10.1002/anie.202218606
复制
发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Hou Zhaomin
中科院分区：
文献类型：
--
作者：
Zhuo Qingde;Zhou Xiaoxi;Shima Takanori;Hou Zhaomin
二氮（N2）的活化和功能化具有根本意义和实际重要性。本综述重点关注由过渡金属配合物介导的 N2 活化和不饱和底物的加成，包括一氧化碳、二氧化碳、杂丙二烯、醛、酮、酰基卤、腈、炔烃和丙二烯，提供了各种 N−C 键形成产物。重点放在反应模式和机制上。我们希望这项工作能够激发在这个充满挑战的领域的进一步探索。
Dinitrogen (N2) activation and functionalization is of fundamental interest and practical importance. This review focuses on N2activation and addition to unsaturated substrates, including carbon monoxide, carbon dioxide, heteroallenes, aldehydes, ketones, acid halides, nitriles, alkynes, and allenes, mediated by transition metal complexes, which afforded a variety of N−C bond formation products. Emphases are placed on the reaction modes and mechanisms. We hope that this work would stimulate further explorations in this challenging field.