catena-Poly[[copper(I)-bis[μ-bis(di-phenyl-phos-phino)methane-κP:P']-copper(I)-μ-2,2'-bipyridine-κN:N'] bis(tetra-fluorido-borate) dichloromethane 2.5-solvate].
catena-Poly[[copper(I)-bis[μ-bis(di-phenyl-phos-phino)methane-κP:P']-copper(I)-μ-2,2'-bipyridine-κN:N'] bis(tetra-fluorido-borate) dichloromethane 2.5-solvate].
复制标题
链状聚[[铜(I)-双[μ-双(二苯基膦)甲烷-μP:P]-铜(I)-μ-2,2-联吡啶-μN:N
DOI：
10.1107/s1600536808001530
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发表时间：
2008
期刊：
影响因子：
--
通讯作者：
Pan,Yu-Shan
中科院分区：
文献类型：
--
作者：
Mo,Juan;Hu,Gong-Zheng;Chen,Wen;Yuan,Li;Pan,Yu-Shan
The title complex, {[Cu2(C10H8N2)(C25H22P2)2](BF4)2·2.5CH2Cl2}n, contains chains of CuI centres bridged alternately by two (diphenylphosphino)methane (dppm) and 4,4′-bipyridine (bpy) ligands. Each CuI atom is coordinated by one N atom of 4,4′-bipyridine (bpy) and two P atoms of two (diphenylphosphino)methane (dppm) ligand, and has a trigonal-planar coordination geometry. There is an inversion centre midway between each pair of adjacent Cu atoms. The distance of two CuI atoms separated by two (diphenylphosphino)methane bridging ligands is 3.732 (3) Å, and 4,4′-bipyridine 11.138 (5) Å.
