Conversion of Allylic Alcohols to Stereodefined Trisubstituted Alkenes: A Complementary Process to the Claisen Rearrangement
Conversion of Allylic Alcohols to Stereodefined Trisubstituted Alkenes: A Complementary Process to the Claisen Rearrangement
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DOI：
10.1021/ja8074242
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发表时间：
2008-12-17
影响因子：
15
通讯作者：
Micalizio, Glenn C.
中科院分区：
文献类型：
--
作者：
Belardi, Justin K.;Micalizio, Glenn C.
报道了一种立体选择性地将烯丙醇转化为（Z）-三取代烯烃的方法。总体而言，所描述的反应顺序与相关的克莱森重排反应过程在立体化学上互补，这些反应过程通常会产生含有立体异构三取代烯烃的产物。
A stereoselective method for the conversion of allylic alcohols to (Z)-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complementary to related Claisen rearrangement reactions processes that typically deliver the stereoisomeric trisubstituted alkene containing products.