Ferrocenyl-substituted low-coordinated heavier group 14 elements
Ferrocenyl-substituted low-coordinated heavier group 14 elements
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二茂铁基取代的低配位重14族元素
DOI：
10.1039/d0dt01426e
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发表时间：
2020
影响因子：
4
通讯作者：
Sasamori Takahiro
中科院分区：
文献类型：
--
作者：
Takeuchi Hironori;Fujimori Yusuke;Ueda Yoshihiro;Shibayama Hiromitsu;Nagaishi Masaru;Yoshimura Tomoyuki;Sasamori Takahiro;Tokitoh Norihiro;Furuta Takumi;Kawabata Takeo;Sasamori Takahiro
报道了几个重14族元素(Si、Ge、Sb、Pb)的稳定低配位物种，如二价物种和多键化合物。考虑到创造前所未有的重14族元素的低配位物种，表现出显著提高的氧化还原稳定性，设计了二茂铁(FC)取代的重14族元素的低配位物种。本文综述了近几年来FC基重14族元素低配位物种的合成研究进展。
Several examples of stable low-coordinated species of heavier group 14 elements (Si, Ge, Sb, Pb) such as divalent species and multiple-bond compounds have been reported. With the goal in mind to create unprecedented low-coordinated species of heavier group 14 elements that exhibit considerably increased redox stability, ferrocenyl (Fc)-substituted low-coordinated species of heavier group 14 elements were designed. In this short account article, recent progress on the synthesis of Fc-based low-coordinated species of heavier group 14 elements is summarized.