Pd(OAc)(2)-catalyzed synthesis of benzyl phenyl ether derivatives with H2O2 as an oxidant in neat water
Pd(OAc)(2)-catalyzed synthesis of benzyl phenyl ether derivatives with H2O2 as an oxidant in neat water
复制标题
Pd(OAc)(2)催化纯水中H2O2为氧化剂合成苄基苯基醚衍生物
DOI：
10.1016/j.catcom.2018.10.026
复制
发表时间：
2019
影响因子：
3.7
通讯作者：
Yang Jian Xin
中科院分区：
文献类型：
--
作者：
Chen Qian Qian;Zhang Hui Xian;Yang Jian Xin
A new protocol for Pd(OAc)2-catalyzed reactions of different benzyl bromides and various arylboronic acids has been developed to form functionalized benzyl phenyl ethers. This method represents the first instance where arylboronic acid is used as a reaction substrate for benzyl phenyl ether synthesis with H2O2as the green oxidant under atmospheric oxygen and pure H2O as an environmental friendly solvent without the requirement for phosphine- and N-based ligands, remarkable functional group tolerance, and considerable yield.
