Systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a pentlandite-like M8S6 core.

Systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a pentlandite-like M8S6 core.
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DOI:
10.1021/ja042938o
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发表时间:
2005-03
影响因子:
15
通讯作者:
M. Koutmos;Harris Kalyvas;Y. Sanakis;A. Simopoulos;D. Coucouvanis
M. Koutmos;Harris Kalyvas;Y. Sanakis;A. Simopoulos;D. Coucouvanis
中科院分区:
化学1区
文献类型:
--
作者:
M. Koutmos;Harris Kalyvas;Y. Sanakis;A. Simopoulos;D. Coucouvanis

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The systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a M8S6 core structure that resembles that of pentlandite minerals is described. The chemical properties and electronic structures of the new clusters have been investigated and are reported in this communication.