Simultaneous determination of nitrilotriacetic acid, ethylenediaminetetra-acetic acid and diethylenetriaminepenta-acetic acid as their methyl ester derivatives by GLC

Simultaneous determination of nitrilotriacetic acid, ethylenediaminetetra-acetic acid and diethylenetriaminepenta-acetic acid as their methyl ester derivatives by GLC
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气相色谱法同时测定次氮基三乙酸、乙二胺四乙酸和二亚乙基三胺五乙酸的甲酯衍生物

DOI:
10.1016/0043-1354(72)90039-5
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发表时间:
1972
期刊:
影响因子:
12.8
通讯作者:
L. Rudling
L. Rudling
中科院分区:
环境科学与生态学1区
文献类型:
--
作者:
L. Rudling

文献摘要

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报道了一种测定硝基三乙酸(NTA)、乙二胺四乙酸(EDTA)和二乙三胺五乙酸(DTPA)的专用方法。水样,蒸发至干燥后,用甲醇/三氟化硼混合物处理。所得的甲酯衍生物经GLC分析。EDTA和DTPA的浓度可低至0.01 mg 1−1,NTA的浓度可低至0.2 mg 1−1。
A specific method for the determination of nitrilotriacetic acid (NTA), ethylenediaminetetra-acetic acid (EDTA) and diethylenetriaminepenta-acetic acid (DTPA) is reported. The aqueous sample, after evaporation to dryness, is treated with a methanol/borontrifluoride mixture. The resulting methyl ester derivatives are analysed by GLC. Concentrations down to 0·01 mg 1−1for EDTA and DTPA, and 0·2 mg 1−1for NTA, can be determined.