Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines
Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines
复制标题
DOI：
10.1039/b805606d
复制
发表时间：
2008-01-01
影响因子：
4.9
通讯作者：
Mulvey, Robert E.
中科院分区：
文献类型：
--
作者：
Conway, Ben;Graham, David V.;Mulvey, Robert E.
新的协同碱[PMDET中心点AK(TMP)(Et)Zn(Et)]选择性地将4-二甲氨基吡啶和4-甲氧基吡啶分别镀在2-位和4-甲氧基吡啶上，得到了两种不同结构的双金属吡啶锌钾络合物。
The new synergic base [PMDET center dot AK(TMP)(Et) Zn(Et)] selectively zincates 4-(dimethylamino) pyridine at the 2-position and 4- methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure.