Supramolecular isomers in the same crystal: a new type of entanglement involving ribbons of rings and 2D (4,4) networks polycatenated in a 3D architecture.

Supramolecular isomers in the same crystal: a new type of entanglement involving ribbons of rings and 2D (4,4) networks polycatenated in a 3D architecture.
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DOI:
10.1039/b418392d
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发表时间:
2005-05
影响因子:
4.9
通讯作者:
Bao-Zong Li;Yanfen Peng;B. Li;Yong Zhang
Bao-Zong Li;Yanfen Peng;B. Li;Yong Zhang
中科院分区:
化学2区
文献类型:
--
作者:
Bao-Zong Li;Yanfen Peng;B. Li;Yong Zhang

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相应的镉盐与柔性配体1,4-bis的反应(1,2,4-三唑-1-基甲基)苯(bbtz)得到三维配位网络[Cd 3(bbtz)6(H2O)6](BF 4)(6.1.75 H2O(1),含有彼此多链连接的环带状物和平面2D(4,4)网络,波状2D(4,(4)网状结构[Cd(bbtz)2(H2O)2](ClO 4)2·2 H2O(2)和环状带状结构[Cd(bbtz)2(H2O)2](BF 4)2·3DMF(3)和环状带状结构[Cd(bbtz)2(H2O)2](ClO 4)2·3DMF(4)。
The reaction of corresponding cadmium salts with the flexible ligand 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) affords the 3D coordination network [Cd3(bbtz)6(H2O)6](BF4)(6.1.75H2O (1), containing ribbons of rings and planar 2D (4,4) networks polycatenated with each other, the undulating 2D (4,4) network [Cd(bbtz)2(H2O)2](ClO4)2.2H2O (2), and ribbons of rings [Cd(bbtz)2(H2O)2](BF4)2.3DMF (3) and [Cd(bbtz)2(H2O)2](ClO4)2.3DMF (4).