Ethylene oligomerization on Ni 2+ single sites within lacunary defects of Wells Dawson polyoxometalates
Ethylene oligomerization on Ni 2+ single sites within lacunary defects of Wells Dawson polyoxometalates
复制标题
Wells Dawson 多金属氧酸盐的空洞缺陷内 Ni 2 单位点上的乙烯齐聚
DOI：
10.1039/d1cc05377a
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发表时间：
2021
影响因子：
4.9
通讯作者：
Hicks, Jason C.
中科院分区：
文献类型：
--
作者：
Cho, Yoonrae;Muhlenkamp, Jessica A.;Oliver, Allen G.;Hicks, Jason C.
轻质烯烃的低聚已成为将气态烯烃转化为液体燃料和增值化学品的重要步骤。在这里，我们报告了在 Wells Dawson 多金属氧酸盐缺陷上分离的镍单中心的合成和应用，作为稳定且可再生的乙烯低聚催化剂。
Oligomerization of light olefins has become an essential step to convert gaseous olefins to liquid fuels and value-added chemicals. Here, we report the synthesis and application of nickel single sites isolated on Wells Dawson polyoxometalate defects as stable and regenerable catalysts for ethylene oligomerization.