Synthesis and chemical stability of technetium nitrides
Synthesis and chemical stability of technetium nitrides
复制标题
氮化锝的合成及化学稳定性
DOI：
10.1039/d1cc02525b
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发表时间：
2021
影响因子：
4.9
通讯作者：
Forster, Paul M.
中科院分区：
文献类型：
--
作者：
Siska, Emily;Smith, Dean;Salamat, Ashkan;Lawler, Keith V.;Lavina, Barbara;Poineau, Frederic;Forster, Paul M.
我们证明了合成和相稳定性的TcN，Tc2N，和亚化学计量TcNx从0到50 GPa和2500 K在激光加热的金刚石对顶砧单元。至少证明了每种化合物的潜在可回收性。TcN采用通过晶体结构预测识别的先前未预测的结构。
We demonstrate the synthesis and phase stability of TcN, Tc2N, and a substoichiometric TcNx from 0 to 50 GPa and to 2500 K in a laser-heated diamond anvil cell. At least potential recoverability is demonstrated for each compound. TcN adopts a previously unpredicted structure identified via crystal structure prediction.