Unique spin transition and wide thermal hysteresis loop for a cobalt(II) compound with long alkyl chain

Unique spin transition and wide thermal hysteresis loop for a cobalt(II) compound with long alkyl chain
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DOI:
10.1039/c0dt01052a
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发表时间:
2011-01-01
影响因子:
4
通讯作者:
Ohba, Masaaki
Ohba, Masaaki
中科院分区:
化学2区
文献类型:
--
作者:
Hayami, Shinya;Kato, Kazuya;Ohba, Masaaki

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合成并表征了具有长烷基链的钴(II)化合物[Co(C12-terpy)(2)](BF 4)(2)中心点EtOH中心点0.5H(2)O(1中心点EtOH中心点0.5H(2)O)和[Co(C12-terpy)(2)](BF 4)(2)(1)。化合物1中心点EtOH中心点0.5H(2)O表现出“再入自旋交叉”。化合物1表现出重入式自旋交叉和具有宽热滞回线的多相转变。
The cobalt(II) compounds with long alkyl chains, [Co(C12-terpy)(2)](BF4)(2)center dot EtOH center dot 0.5H(2)O(1 center dot EtOH center dot 0.5H(2)O) and [Co(C12-terpy)(2)](BF4)(2) (1) was synthesized and characterized. The compound 1 center dot EtOH center dot 0.5H(2)O exhibits a "re-entrant spin crossover". The compound 1 exhibits the re-entrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.