REVISED STRUCTURE OF THE FUNGAL GERMINATION SELF-INHIBITOR GLOEOSPORONE
REVISED STRUCTURE OF THE FUNGAL GERMINATION SELF-INHIBITOR GLOEOSPORONE
复制标题
DOI：
10.1002/hlca.19870700203
复制
发表时间：
1987-01-01
影响因子：
1.8
通讯作者：
KELLY, SE
中科院分区：
文献类型：
--
作者：
MEYER, WL;SCHWEIZER, WB;KELLY, SE
Gloeosporone，来自真菌 Colletotrichum gloeosporioides f 的发芽自抑制剂。 sp。通过光谱数据和X射线分析显示，jussiaea具有如式2所示的结构和相对构型((1S，6R，12R)-1-羟基-6-戊基-5，15-二氧杂二环[10.2.1]十五烷-4，13-二酮或其对映体)，而不是先前指定的结构I。
Gloeosporone, the germination self-inhibitor from the fungus Colletotrichum gloeosporioides f. sp. jussiaea, is shown by spectroscopic data and X-ray analysis to have the constitution and relative configuration as shown in Formula 2 (either (1S,6R,12R)-1-hydroxy-6-pentyl-5,15-dioxabicyclo[10.2.1]pentadecan-4,13-dione or its enantiomer), rather than the previously assigned constitution I.