Supramolecular routes towards liquid crystalline side-chain polymers.
Supramolecular routes towards liquid crystalline side-chain polymers.
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DOI：
10.1039/b719672e
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发表时间：
2008-04
期刊：
影响因子：
3.4
通讯作者：
M. Hammond;R. Mezzenga
中科院分区：
文献类型：
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作者：
M. Hammond;R. Mezzenga
介晶或非介晶侧链与聚合物主链的超分子连接可导致液晶形态的形成。为了实现这些形态，可以调整的各种参数，例如非共价键化学的类型(氢键、离子键、金属配位、π-π相互作用)、聚合物模板结构以及侧链结构和性质，在下文中进行了综述，重点是这些参数在确定最终材料形态和性质中所起的作用。
Supramolecular attachment of mesogenic or non-mesogenic side chains to polymer backbones can result in the formation of liquid crystalline morphologies. The various parameters that can be tuned in order to achieve these morphologies, such as the type of non-covalent bonding chemistry (hydrogen bonding, ionic bonding, metal coordination, π-π interactions), the polymeric template architecture, and the side chain structure and properties, are reviewed in what follows, with emphasis placed on the role these parameters play in the determination of the final material morphologies and properties.