Crystal structures and magnetic properties of chiral and achiral cyanide-bridged bimetallic layered compounds
Crystal structures and magnetic properties of chiral and achiral cyanide-bridged bimetallic layered compounds
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DOI：
10.1016/j.poly.2005.03.159
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发表时间：
2005-11
期刊：
影响因子：
2.6
通讯作者：
H. Imai;K. Inoue;K. Kikuchi
中科院分区：
文献类型：
--
作者：
H. Imai;K. Inoue;K. Kikuchi
研究了手性和非手性层状化合物[Cr（CN）6][Mn（R）-pnH（DMF）]·（2 H2O）（1）和[Cr（CN）6][Mn（racemi）-pnH（DMF）]·（2 H2O）（2）的晶体结构和磁性。X-射线结构分析表明，这两种化合物含有类似的氰化物桥连折叠。磁性测量表明化合物1和2在30 K以下分别表现为变磁体和亚铁磁体。
The crystal structures and magnetic properties of chiral and achiral bimetallic layered compounds, [Cr(CN)6][Mn(R)-pnH(DMF)]·(2H2O) (1) and [Cr(CN)6][Mn(racemi)-pnH(DMF)]·(2H2O) (2) have been studied. X-ray structural analyses reveal that both compounds contain similar cyanide-bridged bimetallic sheet. The magnetic measurements demonstrate that compounds 1 and 2 behave as metamagnet and ferrimagnet below 30K, respectively.