A Nickel Catalyst for the Addition of Organoboronate Esters to Ketones and Aldehydes
A Nickel Catalyst for the Addition of Organoboronate Esters to Ketones and Aldehydes
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DOI：
10.1021/ol9017613
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发表时间：
2009-10-01
期刊：
影响因子：
5.2
通讯作者：
Itami, Kenichiro
中科院分区：
文献类型：
--
作者：
Bouffard, Jean;Itami, Kenichiro
Ni(cod)(2)/IPr催化剂促进了芳基硼酸酯与非活化醛和酮的分子间1,2加成反应。二芳基酮、烷基芳基酮和二烷基酮在温和的反应条件下表现出良好的反应活性(
A Ni(cod)(2)/IPr catalyst promotes the intermolecular 1,2-addition of arylboronate esters to unactivated aldehydes and ketones. Diaryl, alkyl aryl, and dialkyl ketones show good reactivity under mild reaction conditions (