Antimicrobial finishing of acrilan fabrics with cetylpyridinium chloride: Affected properties and structures
Antimicrobial finishing of acrilan fabrics with cetylpyridinium chloride: Affected properties and structures
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DOI：
10.1002/app.21261
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发表时间：
2005-08-05
影响因子：
3
通讯作者：
Sun, G
中科院分区：
文献类型：
--
作者：
Cai, ZS;Sun, G
通过在化学整理过程中使用氯化十六烷基吡啶 (CPC) 制备耐用的抗菌 acrilan 织物。 CPC可以与acrilan纤维上的阴离子基团形成离子相互作用，这有助于持久的抗菌功能。化学处理的 pH、温度和时间等反应条件会影响 CPC 的消耗和抗菌性能。然而，整理浴的 pH 条件也会影响织物的机械性能和颜色，特别是在碱性条件下。虽然为了获得持久的抗菌功能，更偏碱性的条件是优选的，但高 pH 值会降低拉伸强度并导致丙烯酰胺纤维泛黄。丙烯腈纤维的泛黄是由丙烯腈基团的水解和聚合物中共轭C=N体系的形成引起的。通过 FTIR 表征了共轭体系。 (c) 2005 年 Wiley 期刊公司。
Durable antimicrobial acrilan fabrics were prepared by using cetylpyridinium chloride (CPC) in a chemical finishing process. The CPC could form ionic interactions, with anionic groups on acrilan fibers, which contribute to durable antimicrobial functions. Reaction conditions such as pH, temperature, and time of the chemical treatment affected exhaustion of CPC and antimicrobial properties. However, the pH conditions of the finishing bath also impacted mechanical properties and color of the fabrics, particularly under alkaline conditions. Although a more alkaline condition is preferred for durable antimicrobial functions, high pH reduces tensile strength and results in yellowing of acrilan fibers. The yellowing of the acrilan fibers is caused by the hydrolysis of acrylonitrle groups and induced formation of conjugated C=N systems in the polymers. The conjugated systems were characterized by FTIR. (c) 2005 Wiley Periodicals, Inc.