Perhydrolysis in Ethereal H2O2 Mediated by MoO2(acac)2: Distinct Chemoselectivity between Ketones, Ketals, and Epoxides
Perhydrolysis in Ethereal H2O2 Mediated by MoO2(acac)2: Distinct Chemoselectivity between Ketones, Ketals, and Epoxides
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MoO2(acac)(2) 介导的乙醚 H2O2 过水解反应：酮、缩酮和环氧化物之间独特的化学选择性
DOI：
10.1021/acs.orglett.9b00425
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发表时间：
2019-03-01
期刊：
影响因子：
5.2
通讯作者：
Wu, Yikang
中科院分区：
文献类型：
--
作者：
An, Xiaosheng;Zha, Qinghong;Wu, Yikang
在催化量的MoO2（acac）（2）存在下，酮、缩酮和环氧化物通过与醚H2O2反应以高产率转化为相应的氢过氧化物，具有明显的（迄今为止无法达到的）化学选择性。
Ketones, ketals, and epoxides were converted into corresponding hydroperoxides in high yields by reaction with ethereal H2O2 in the presence of a catalytic amount of MoO2(acac)(2) with distinct (to date unattainable) chemoselectivity.