Micro-tubular solid oxide fuel cells fabricated by phase-inversion method

Micro-tubular solid oxide fuel cells fabricated by phase-inversion method
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DOI:
10.1016/j.elecom.2010.02.024
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发表时间:
2010-05
影响因子:
5.4
通讯作者:
Chenghao Yang;C. Jin;F. Chen
Chenghao Yang;C. Jin;F. Chen
中科院分区:
工程技术3区
文献类型:
--
作者:
Chenghao Yang;C. Jin;F. Chen

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采用相转化、浸渍涂层和高温共烧相结合的方法,将电极催化剂浸渍到多孔电极基质中,制备了一种新型结构微管固体氧化物燃料电池(MT SOFC)。用相转化法制备的非对称多孔阳极分为两层,厚的燃料传输层具有大的指状孔,而薄的功能层具有小的指状孔。MT-SOFC的最大功率密度分别为0.44、0.54、0.65和0.78W/cm2,温度分别为650、700、750和800°C,燃料为H2-15%H2O,空气为氧化剂。新型结构MT-SOFC将功率输出与快速启动行为相结合,为快速启动高性能功率器件提供了一种潜在的解决方案。
A novel structured micro-tubular solid oxide fuel cell (MT-SOFC) has been fabricated by combining a phase-inversion, dip-coating and high temperature co-sintering process with impregnation of the electrode catalyst into a porous electrode matrix. The asymmetric porous anode made by phase-inversion is divided into two different layers, a thick fuel delivery layer with large finger-like pores and a thin function layer with small finger-like pores. The MT-SOFC demonstrates maximum power densities of 0.44, 0.54, 0.65 and 0.78W/cm2at 650, 700, 750 and 800°C, respectively with H2–15%H2O as fuel and ambient air as oxidant. Combining the power output with the quick start-up behavior, novel structured MT-SOFC offers a potential solution for rapid start-up high performance power devices.