Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcohol

Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcohol
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DOI:
10.1039/c6gc00623j
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发表时间:
2016-01-01
期刊:
影响因子:
9.8
通讯作者:
North, Michael
North, Michael
中科院分区:
化学1区
文献类型:
--
作者:
Bai, Yinjuan;De Bruyn, Mario;North, Michael

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A new oxa-norbornene bio-based lactone obtained from the 100% atom economic reaction of furfuryl alcohol and itaconic anhydride via a tandem Diels-Alder addition and lactonisation is presented. Esterification of the resulting acid gives a monomer for the production of a bio-based polymer with low polydispersity and well controlled molecular weight via ring-opening metathesis polymerisation (ROMP).