A general and facile strategy for precisely controlling the crystal size of monodispersed metal-organic frameworks via separating the nucleation and growth.
A general and facile strategy for precisely controlling the crystal size of monodispersed metal-organic frameworks via separating the nucleation and growth.
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DOI：
10.1039/c7cc08244d
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发表时间：
2018-01
影响因子：
4.9
通讯作者：
Xiaocheng Lan;Ning-Kang Huang;Jin-fu Wang;Tiefeng Wang
中科院分区：
文献类型：
--
作者：
Xiaocheng Lan;Ning-Kang Huang;Jin-fu Wang;Tiefeng Wang
提出了一种新颖易行的方法，通过分离成核和生长来精确控制ZIF-8、ZnCo双金属zif的晶体尺寸和NPs@ZIF-8。详细研究了该策略结晶的基本原理，并探讨了尺寸对一系列Pt@ZIF-8催化剂内部扩散的影响。
A novel and facile strategy was proposed for precisely controlling the crystal size of ZIF-8, ZnCo bimetallic ZIFs and also NPs@ZIF-8 by separating the nucleation and growth. The fundamentals of crystallization of this strategy were elaborately investigated, and the size effect on the internal diffusion was explored for a series of Pt@ZIF-8 catalysts.