Complex Formation between Iron(III) and Tartaric and Citric Acids in a Wide pH Range 1 to 13 as Studied by Magnetic Susceptibility Measurements
Complex Formation between Iron(III) and Tartaric and Citric Acids in a Wide pH Range 1 to 13 as Studied by Magnetic Susceptibility Measurements
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通过磁化率测量研究铁 (III) 与酒石酸和柠檬酸在 1 至 13 的宽 pH 范围内形成络合物
DOI：
10.1246/cl.1994.281
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发表时间：
1994
期刊：
影响因子：
--
通讯作者：
S. Kawata
中科院分区：
文献类型：
--
作者：
H. Yokoi;T. Mitani;Yasuyoshi Mori;S. Kawata
对不同浓度比的铁(III)和L-酒石酸或柠檬酸水溶液的有效磁矩与pH值的实验图进行计算机模拟分析，首次给出了在室温下1至13的宽pH范围内络合物形成的全部情况。在这些溶液中已经阐明了各种多核和单核络合物的形成。
Computer simulation analysis of the experimental plots of effective magnetic moment against pH for aqueous solutions of iron(III) and either L-tartaric acid or citric acid at different concentration ratios has first given the whole aspect of complex formation in a wide pH range 1 to 13 at room temperature. Formation of various kinds of poly- and mono-nuclear complexes has been elucidated in these solutions.