Recent Advances in the Synthesis and Applications of Organoborane Polymers
Recent Advances in the Synthesis and Applications of Organoborane Polymers
复制标题
DOI：
10.1007/978-3-319-13054-5_10
复制
发表时间：
2015-01-01
期刊：
影响因子：
--
通讯作者：
Jaekle, Frieder
中科院分区：
文献类型：
--
作者：
Jaekle, Frieder
本章综述了有机硼烷聚合物合成的最新进展。在过去的十年里，见证了功能硼烷单体直接聚合的新方法以及创新的聚合物改性技术的使用。还开发了强大的新方法，允许将官能化的硼烷部分定位在聚合物链中明确定义的位置。合成的有机硼烷聚合物已被用作发光和电活性材料、电池电解液、负载型Lewis酸催化剂、阴离子和生物相关分子的传感器、刺激响应和动态(超分子)材料的构建块，以及生物医学应用。
Recent advances in the synthesis of organoborane polymers are reviewed in this chapter. The last decade has witnessed new approaches for the direct polymerization of functional borane monomers as well as the use of innovative polymer modification techniques. Powerful new methods that allow for positioning of functional borane moieties at well-defined positions in the polymer chain have also been developed. The resulting organoborane polymers have been investigated as luminescent and electro-active materials, electrolytes for batteries, supported Lewis acid catalysts, sensors for anions and biologically relevant molecules, building blocks of stimuli-responsive and dynamic (supramolecular) materials, and for biomedical applications.