Counterions of BINAP-Pt(II) and -Pd(II) complexes: novel catalysts for highly enantioselective Diels-Alder reaction.
Counterions of BINAP-Pt(II) and -Pd(II) complexes: novel catalysts for highly enantioselective Diels-Alder reaction.
复制标题
BINAP-Pt(II) 和-Pd(II) 配合物的抗衡离子：用于高度对映选择性狄尔斯-阿尔德反应的新型催化剂。
DOI：
10.1021/ol990346i
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发表时间：
1999
期刊：
影响因子：
5.2
通讯作者：
Matsuda,H
中科院分区：
文献类型：
--
作者：
Ghosh,AK;Matsuda,H
Platinum and palladium chiral bisphosphine complexes and their counterion effects in asymmetric Diels−Alder reactions have been investigated. The reaction of cyclopentadiene and various bidentate dienophiles in the presence of a catalytic amount of Pt(II)− or Pd(II)−BINAP complex proceeds with excellentendo/exoselectivity as well asendoenantioselectivity (up to 99% ee).
