Acid-Catalyzed Oxidative Cross-Coupling of Acridans with Silyl Diazoenolates and Rh-Catalyzed Rearrangement: Two-step Synthesis of γ-(9-Acridanylidene)-β-keto Esters
Acid-Catalyzed Oxidative Cross-Coupling of Acridans with Silyl Diazoenolates and Rh-Catalyzed Rearrangement: Two-step Synthesis of γ-(9-Acridanylidene)-β-keto Esters
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Acridans 与甲硅烷基重氮烯醇盐的酸催化氧化交叉偶联和 Rh 催化重排：γ-(9-Acridanylidene)-β-酮酯的两步合成
DOI：
10.1039/d1ob00691f
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发表时间：
2021
期刊：
影响因子：
--
通讯作者：
Lei Zhou
中科院分区：
文献类型：
--
作者：
Wei-Yu Li;Hao Xu;Lei Zhou
描述了吖啶类和甲硅烷基重氮烯醇盐的 MsOH 催化氧化交叉偶联以及所得重氮产物的 Rh2(OAc)4 催化重排。该反应以良好的产率提供各种 γ-(9-吖啶基)-β-酮酯，其具有...
A MsOH-catalyzed oxidative cross-coupling of acridans and silyl diazoenolates and Rh2(OAc)4-catalyzed rearrangement of the resultant diazo products were described. The reactions provide various γ-(9-acridanylidene)-β-keto esters in good yields, which bear...