Accelerated asymmetric transfer hydrogenation of aromatic ketones in water.

Accelerated asymmetric transfer hydrogenation of aromatic ketones in water.
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DOI:
10.1039/b403627a
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发表时间:
2004-06
影响因子:
3.2
通讯作者:
Xiaofeng Wu;Xiaoguang Li;W. Hems;F. King;Jianliang Xiao
Xiaofeng Wu;Xiaoguang Li;W. Hems;F. King;Jianliang Xiao
中科院分区:
化学3区
文献类型:
--
作者:
Xiaofeng Wu;Xiaoguang Li;W. Hems;F. King;Jianliang Xiao

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Asymmetric transfer hydrogenation of various simple aromatic ketones by the Ru-TsDPEN catalyst was shown to be feasible in aqueous HCOONa without calling for any catalyst modification, furnishing ee's of up to 95% and significantly faster rates than in the HCOOH-NEt(3) azeotrope.