Unveiling the abnormal effect of temperature on enantioselectivity in the palladium-mediated decabonylative alkylation of MBH acetate
Unveiling the abnormal effect of temperature on enantioselectivity in the palladium-mediated decabonylative alkylation of MBH acetate
复制标题
DOI：
10.1039/d1qo00782c
复制
发表时间：
2021-07
影响因子：
5.4
通讯作者：
Xiangrui Zheng;Kai Chen;Jun‐An Xiao;Jun Li;Sha-Sha Wang-Sha;Qinglan Zhao;H. Xiang;Xiaoqing Chen;Hua Yang
中科院分区：
文献类型：
--
作者：
Xiangrui Zheng;Kai Chen;Jun‐An Xiao;Jun Li;Sha-Sha Wang-Sha;Qinglan Zhao;H. Xiang;Xiaoqing Chen;Hua Yang
在钯催化的环状Morita-Baylis-Hillman乙酸酯和4，4，4-三氟-1-苯基-1，3-丁二酮的对映体亲核取代反应中，观察到了一种不寻常的温度-对映体选择性关系。
An unusual temperature–enantioselectivity relationship was observed in the newly developed palladium-catalysed enantioselective nucleophilic substitution of cyclic Morita–Baylis–Hillman acetate and 4,4,4-trifluoro-1-phenyl-1,3-butanedione.