Size-controlled synthesis of near-monodisperse gold nanoparticles in the 1-4 nm range using polymeric stabilizers

Size-controlled synthesis of near-monodisperse gold nanoparticles in the 1-4 nm range using polymeric stabilizers
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DOI:
10.1021/ja055321v
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发表时间:
2005-11-30
影响因子:
15
通讯作者:
Brust, M
Brust, M
中科院分区:
化学1区
文献类型:
--
作者:
Hussain, I;Graham, S;Brust, M

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我们在这里报告了一个简单的一步制备近单分散的金水溶胶在小尺寸制度(<5 nm)的协议。可以通过改变稳定聚合物的浓度来控制粒度,稳定聚合物可以容易地被硫醇配体置换以产生通常类型的单层保护簇。
We report here a simple one-step protocol for the preparation of near-monodisperse gold hydrosols in the small size regime (<5 nm). The particle size can be controlled by varying the concentration of the stabilizing polymer, which can be readily displaced by thiol ligands to yield monolayer protected clusters of the usual type.