Kinetic study of methanol synthesis from carbon dioxide and hydrogen
Kinetic study of methanol synthesis from carbon dioxide and hydrogen
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二氧化碳和氢气合成甲醇的动力学研究
DOI：
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发表时间：
2001
期刊：
影响因子：
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通讯作者：
M. Saito
中科院分区：
文献类型：
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作者：
T. Kubota;I. Hayakawa;H. Mabuse;Kozo Mori;K. Ushikoshi;Taiki Watanabe;M. Saito
CO2加氢合成甲醇的实用动力学方程是设计高效反应器所必需的。从甲醇合成和CO生成的反应机理以及在我们的Cu/ZnO基催化剂上的各种动力学实验中推导出动力学方程。通过将动力学方程计算值与试验装置（50 kg/天MeOH）中各种实验获得的数据进行比较，验证了推导方程的准确性。 因此，在本研究中开发的动力学方程已被发现适用于设计一个高效的反应器，采用我们开发的催化剂。版权所有© 2001约翰威利父子有限公司。
Practical kinetic equations for methanol synthesis from CO2 hydrogenation are necessary for designing a highly efficient reactor. The kinetic equations were deduced from the reaction mechanisms for methanol synthesis and CO formation as well as from various kinetic experiments over our Cu/ZnO-based catalyst. The accuracy of the equations deduced has been verified by the comparison between the values calculated from the kinetic equations and the data obtained from various experiments in a test plant (50 kg day−1 of MeOH). Therefore, the kinetic equations developed in the present study have been found applicable to the design of a highly effective reactor employing our developed catalyst. Copyright © 2001 John Wiley & Sons, Ltd.