Poly (phthalazinone ether sulfone ketone) properties and their effect on the membrane morphology and performance

Poly (phthalazinone ether sulfone ketone) properties and their effect on the membrane morphology and performance
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聚二氮杂萘酮醚砜酮的性质及其对膜形貌和性能的影响

DOI:
10.5004/dwt.2009.793
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发表时间:
2009-11
影响因子:
1.1
通讯作者:
Han,B.
Han,B.
中科院分区:
工程技术4区
文献类型:
--
作者:
Sun,B.;Chen,C.;Takuji,S.;Li,J.;Qin,P.;Han,B.

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聚芳醚砜酮(PPESK)是一种相对较新的材料,它含有一定量的4-(4-羟基苯基)-2,3-二氮杂-1-酮,含有不同比例的二苯酮和二苯砜。研究了该共聚物的玻璃化转变温度、特性粘度、差示扫描量热仪(DSC)和傅立叶变换红外光谱等物理化学特性。用几种常用的酸、碱和氧化剂测试了该共聚物的化学稳定性。测定了该共聚物在N-甲基吡咯烷酮(NMP)溶剂中不同浓度和不同温度下的表观粘度。研究了聚乙二醇(1000gmol-1)和吐温80两种添加剂对PPESK/NMP溶液表观粘度的影响。在此基础上,用PPESK/NMP溶液制备了不对称超滤膜,考察了其对超滤膜性能的影响。
Poly (phthalazinone ether sulfone ketone) (PPESK) copolymer is a relatively newly developed material, which contains different component ratios of diphenyl ketone and diphenyl sulfone with respect to a certain amount of 4-(4-hydroxyphenyl)-2,3-phthalazin-1-one. In this study, the physico-chemical characteristics of this copolymer, including the glass transition temperature, the intrinsic viscosity, the DSC (differential scanning calorimeter) and FT-IR spectra have been investigated. The chemical stability of this copolymer has been tested with several commonly used acids, bases and oxidants. The apparent viscosity of this copolymer dissolved in N-methyl pyrrolidone (NMP) solvent at different concentrations and temperatures has been measured. The effect of two additives, polyethylene glycol (1000 g mol-1) and Tween80, on the apparent viscosity of the PPESK/NMP solution, has been investigated. Further, the PPESK/NMP solution has been used to prepare asymmetric ultrafiltration membranes, and the infl uence o...
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