The three-dimensional solubility parameter - key to paint component affinities: solvents, plasticizers, polymers, and resins. II. Dyes, emulsifiers, mutual solubility and compatibility, and pigments. III. Independent cal-culation of the parameter components

The three-dimensional solubility parameter - key to paint component affinities: solvents, plasticizers, polymers, and resins. II. Dyes, emulsifiers, mutual solubility and compatibility, and pigments. III. Independent cal-culation of the parameter components
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发表时间:
1967
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通讯作者:
C. Hansen
C. Hansen
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其他
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作者:
C. Hansen

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本文提出了溶解度参数是由氢键、极性和色散分量组成的矢量的概念,并成功地预测了33种聚合物和树脂在90种溶剂和10种增塑剂中的溶解度。溶解度参数概念的应用进行了说明。在高分子溶解度的基础上,发展了基于同晶概念的三维溶解度参数系统。同样的系统已被应用于染料,非离子乳化剂和颜料的表征。当用一种以上的聚合物溶质配制保护涂层时,该系统也可用于选择溶剂。-- AATA
The concept that the solubility parameter is a vector composed of hydrogen bonding, polar, and dispersion components is proposed and applied with success to prediction of the solubility of 33 poylmers and resins in 90 solvents and 10 plasticizers. The application of the solubility parameter concept is described. The three dimensional solubility parameter system based on the homomorph concept has been developed on the basis of polymer solubility. The same system has been applied to the characterization of dyes, nonionic emulsifiers, and pigments. The system is also useful for selecting solvents when protective coatings are formulated with more than one polymeric solute. -- AATA