A TIME-RESOLVED ELECTRON-NUCLEAR DOUBLE-RESONANCE (ENDOR) STUDY OF THE PHOTOEXCITED TRIPLET-STATE OF FREE-BASE TETRAPHENYLPORPHYRIN
A TIME-RESOLVED ELECTRON-NUCLEAR DOUBLE-RESONANCE (ENDOR) STUDY OF THE PHOTOEXCITED TRIPLET-STATE OF FREE-BASE TETRAPHENYLPORPHYRIN
复制标题
DOI：
10.1016/0927-0248(94)00219-3
复制
发表时间：
1995-08-01
影响因子：
6.9
通讯作者：
MOBIUS, K
中科院分区：
文献类型：
--
作者：
KAY, CWM;DI VALENTIN, M;MOBIUS, K
本文用时间分辨电子核双共振（ENDOR）方法研究了四苯基卟啉在甲苯晶体中的光激发三重态。这允许测量的A（ZZ）超精细张量元素的每一个不同组的等效质子的参考框架中的零场分裂张量。
A time-resolved Electron Nuclear Double Resonance (ENDOR) study has been made of the photo-excited triplet state of free-base tetraphenylporphyrin in a partially aligned sample with crystalline toluene as the host matrix. This has permitted measurement of the A(ZZ) hyperfine tenser elements for each of the different groups of equivalent protons in the reference frame of the zero-field splitting tensor.