CYCLOBUTADIENE PROBLEM
CYCLOBUTADIENE PROBLEM
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DOI：
10.1002/anie.197404251
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发表时间：
1974-01-01
期刊：
影响因子：
--
通讯作者：
MAIER, G
中科院分区：
文献类型：
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作者：
MAIER, G
环丁二烯最近再次成为人们关注的焦点。通过使用基质分离技术，环丁二烯现在可以制备成冷冻在基质中的单体。因此，未取代的母体化合物及其烷基取代的衍生物都值得研究。本进度报告对整个领域进行了调查；然而，特别强调了作者自己对有机化学这一经典问题的研究结果。
Cyclobutadiene has recently become the center of reawakened interest. By use of the matrix isolation technique, cyclobutadienes can now be prepared as monomers frozen in matrices. Thus both the unsubstituted parent compound and its alkyl‐substituted derivatives are amenable to study. The present progress report surveys the entire field; however, particular emphasis is placed on the author's own results from investigations concerning this classical problem of organic chemistry.