Poly(vinylsaccharide)s, 5. Synthesis and characterization of poly(vinylsaccharide)s of the amide type with disaccharides in the side chain
Poly(vinylsaccharide)s, 5. Synthesis and characterization of poly(vinylsaccharide)s of the amide type with disaccharides in the side chain
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聚（乙烯基糖），5.侧链带有二糖的酰胺型聚（乙烯基糖）的合成和表征
DOI：
10.1002/macp.1989.021901018
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发表时间：
1989
影响因子：
2.5
通讯作者：
A. H. Begli
中科院分区：
文献类型：
--
作者：
J. Klein;A. H. Begli
描述了含有二糖单元的定义明确的单乙烯基糖单体的合成。四种不同的单体，N-二糖取代的丙烯酰胺和甲基丙烯酰胺，制备和聚合到相应的聚合物通过自由基聚合在水溶液中使用不同的引发剂系统。通过粘度和光散射测量研究了二糖单元的结构差异对溶液性质的影响。与已知的聚（乙烯基糖）的侧链中的单糖的比较。
The synthesis of well-defined monovinylsaccharide monomers containing disaccharide units is described. Four different monomers, N-disaccharide-substituted acryl- and methacrylamides, were prepared and polymerized to the corresponding polymers by free-radical polymerization in aqueous solution using different initiator systems. The influence of the structural differences of the disaccharide units on the solution properties was studied by viscosity and light scattering measurements. A comparison with known poly(vinylsaccharide)s with monosaccharides in the side chain is made.