Versatile functionalization of polymeric soft materials by implanting various types of dynamic cross-links
Versatile functionalization of polymeric soft materials by implanting various types of dynamic cross-links
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DOI：
10.1038/s41428-021-00474-2
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发表时间：
2021-03
期刊：
影响因子：
2.8
通讯作者：
Mikihiro Hayashi
中科院分区：
文献类型：
--
作者：
Mikihiro Hayashi
本重点综述描述了基于使用各种类型的交联（例如超分子交联、光交联和缔合动态共价键合交联）的聚合物材料的官能化方法。首先，描述了聚合物材料的热性能和机械性能的增强和精确调谐;然后，基于具有关联动态共价键合交联的特殊类型的交联材料（称为玻璃体聚合物）的功能材料的设计和物理性能调谐被证明。这篇综述文章为功能交联材料的制备提供了有用的提示，考虑到对具有多功能物理性能的耐用材料的巨大需求，功能交联材料在现代和未来社会中尤为重要。
The present focus review describes functionalization methods for polymeric materials based on the use of various types of cross-links, such as supramolecular cross-links, photocross-links, and associative dynamic covalent bonded cross-links. First, the enhancement and precise tuning of the thermal and mechanical properties of polymeric materials are described; then, the design and physical property tuning of functional materials based on a special type of cross-linked material with associative dynamic covalent bonded cross-links, known as vitrimers, are demonstrated. This review article provides useful hints for the preparation of functional cross-linked materials, which are especially important in modern and future societies considering the huge demand for durable materials with versatile physical properties.