Sol–Gel Processing of Metal–Organic Frameworks
Sol–Gel Processing of Metal–Organic Frameworks
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DOI：
10.1021/acs.chemmater.6b03934
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发表时间：
2017-03
影响因子：
8.6
通讯作者：
K. Sumida;K. Liang;J. Reboul;Ilich A. Ibarra;S. Furukawa;P. Falcaro
中科院分区：
文献类型：
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作者：
K. Sumida;K. Liang;J. Reboul;Ilich A. Ibarra;S. Furukawa;P. Falcaro
溶胶-凝胶加工代表了一种强大且通用的策略，用于制备功能性无机和杂化材料，有助于控制分子组成，以及与基础和应用研究相关的各种长度尺度的材料组织。最近的进展使其能够用于加工一类新兴的功能性多孔材料，称为金属有机框架（MOF）。在这里，溶胶-凝胶方法可用于直接操纵 MOF，或作为构建复合材料的途径，其中 MOF 的特性与精心选择的无机相的特性协同结合。在这篇综述中，我们根据四种主要合成策略，介绍了这一新兴领域取得的最重大进展，特别重点描述了溶胶-凝胶处理如何增强 MOF 的功能。这些策略包括 (1) 对 MOF 的孔表面进行分子尺度操纵...
Sol–gel processing represents a powerful and versatile strategy for the preparation of functional inorganic and hybrid materials that facilitate control over the molecular composition, as well as organization of the materials at the various length scales relevant to fundamental and applied research. Recent advances have enabled its use for the processing of an emerging class of functional porous materials called metal–organic frameworks (MOFs). Here, sol–gel approaches can be employed for the direct manipulation of MOFs, or as a route to the construction of composite materials where the properties of the MOF are synergistically combined with those of a carefully chosen inorganic phase. In this review, we present the most significant progress made in this emerging area, according to four main synthetic strategies, with a particular focus on describing how sol–gel processing enhances the functionalities of the MOF. These strategies include (1) molecular scale manipulations of the pore surfaces of MOFs with ...