Structure reassignment of the fungal metabolite TAEMC161 as the phytotoxin viridiol
Structure reassignment of the fungal metabolite TAEMC161 as the phytotoxin viridiol
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DOI：
10.1021/np0300277
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发表时间：
2003-05-01
影响因子：
5.1
通讯作者：
Kerekes, AD
中科院分区：
文献类型：
--
作者：
Wipf, P;Kerekes, AD
二维NMR分析（包括HMBC、NOESY和ROESY）以及1D NOE实验导致最近鉴定的钩状木霉代谢物TAEMC 161（1）的结构重新分配为先前已知的viridiol（2）。此外，GIAO计算的C-13 NMR化学位移为1和2提供了强有力的支持修订后的结构。
Two-dimensional NMR analyses including HMBC, NOESY, and ROESY as well as 1D NOE experiments led to a reassignment of the structure of the recently identified Trichoderma hamatum metabolite TAEMC161 (1) as the previously known viridiol (2). In addition, GIAO-calculated C-13 NMR chemical shifts of 1 and 2 provided strong support for the revised structure.