Accelerating Heat-Initiated Radical Reactions of Organic Halides with Tin Hydride Using Flow Microreactor Technologies
Accelerating Heat-Initiated Radical Reactions of Organic Halides with Tin Hydride Using Flow Microreactor Technologies
复制标题
使用流动微反应器技术加速有机卤化物与氢化锡的热引发自由基反应
DOI：
10.1055/s-0040-1707307
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发表时间：
2020
期刊：
影响因子：
2
通讯作者：
Aiichiro Nagaki
中科院分区：
文献类型：
--
作者：
Yiyuan Jiang;Yosuke Ashikari;Kaiteng Guan;Aiichiro Nagaki
本文报道了流动微反应器可以提高自由基链式反应的效率。具有快速传播步骤的链式反应可以通过微反应器的有效传热特性来加速，而具有缓慢传播步骤的那些反应的产率通过流动微反应器来增加。此外，通过顺序加入引发剂进一步提高了产率，这是流动顺序加入系统所允许的。
We herein report that flow microreactors can promote an efficiency of radical chain reactions. The chain reactions with a fast propagation step can be accelerated by virtue of an efficient heat-transfer character of the microreactors, whereas the yield of those reactions with a slow propagation step was increased by flow microreactors. Moreover, the yield was further increased by a sequential addition of the initiators, which was allowed by a flow-sequential-addition system.
利用流动微反应器技术进行自由基化学
DOI：
10.1002/9781119953678.rad035
发表时间：
2012
期刊：
--
影响因子：
--
作者：
T. Fukuyama;I. Ryu
通讯作者：
I. Ryu