Palladium-catalyzed coupling reactions : practical aspects and future developments
Palladium-catalyzed coupling reactions : practical aspects and future developments
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DOI：
10.1002/9783527648283
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发表时间：
2013-04
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影响因子：
--
通讯作者：
Á. Molnár
中科院分区：
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作者：
Á. Molnár
钯催化的碳-碳交叉偶联反应催化剂机理方面未来的挑战高转化率偶联反应中的非均相钯催化剂：Pd负载于脱铝Y型沸石的情况介绍在负载型Pd催化剂上获得高转化数的各种方法超稳Y型沸石的结构和特性Suzuki -Pd/USY催化的Miyaura反应Pd/USY在Mizoroki-Heck反应中的催化性能结论和展望钯催化的偶联反应与可分离的纳米催化剂引言磁性颗粒作为催化剂的一般考虑磁性载体上的钯纳米颗粒磁性载体上的分子钯络合物展望有序多孔固体作为载体材料在钯催化的交叉偶联反应中的应用偶联反应介绍催化剂合成和表征碳-碳偶联杂项偶联反应液相催化问题概述和未来展望聚合物负载催化剂诱导的偶联反应介绍多糖聚（乙二醇）聚苯乙烯聚（苯乙烯）丙烯酰胺聚苯胺聚聚N-乙烯基吡咯烷酮（4-乙烯基吡啶）离子聚合物有机高分子功能化多孔有机高分子杂类聚合物综述与展望离子聚合物中的偶联反应金属络合物金属盐和固体载体上的金属金属纳米颗粒水介质中的交叉偶联反应概述和展望水介质中有机卤化物的交叉偶联以形成C-C键水介质中的碳-杂原子偶联反应C-H水介质中的活化结论和未来展望微波辅助合成C-C和碳-杂原子偶联反应介绍C-C键的形成C-H钯催化的碳-碳偶联反应中的催化剂再循环引言催化剂再循环的一般问题催化剂体系提供高，回收催化剂的稳定产率在回收研究中提供最高的累积吨值总结评价未来展望碳中真正的催化物质的性质-使用非均相钯预催化剂的碳偶联反应介绍Heck反应Suzuki反应Sonogashira反应结束语流动系统介绍流动钯催化剂中的偶联反应流动系统的连续流动技术用于交叉偶联总结和展望钯催化交叉偶联反应-工业应用介绍铃木-宫浦反应Heck -Mizoroki反应Sonogashira - Hagihara反应羰基化氰化Negishi偶联新型Pd催化的C-C交叉偶联反应Buchwald - Hartwig胺化Pd催化的C-S键形成综述与展望
PREFACE PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS - A GENERAL INTRODUCTION Introduction Carbon - Carbon Cross-Coupling Reactions Catalyzed by Palladium The Catalysts Mechanistic Aspects Future Challenges HIGH-TURNOVER HETEROGENEOUS PALLADIUM CATALYSTS IN COUPLING REACTIONS: THE CASE OF PD LOADED ON DEALUMINATED Y ZEOLITES Introduction Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts Structure and Characteristics of Ultrastable Y Zeolites Suzuki - Miyaura Reactions Catalyzed by Pd/USY Catalytic Performance of Pd/USY in Mizoroki - Heck Reactions Conclusion and Perspective PALLADIUM-CATALYZED COUPLING REACTIONS WITH MAGNETICALLY SEPARABLE NANOCATALYSTS Introduction General Considerations Concerning Magnetic Particles as Catalyst Supports Palladium Nanoparticles on Magnetic Supports Molecular Palladium Complexes on Magnetic Supports Outlook THE USE OF ORDERED POROUS SOLIDS AS SUPPORT MATERIALS IN PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS Introduction Catalyst Synthesis and Characterization Carbon - Carbon Couplings Miscellaneous Coupling Reactions The Question of Solution-Phase Catalysis Summary and Future Prospects COUPLING REACTIONS INDUCED BY POLYMER-SUPPORTED CATALYSTS Introduction Polysaccharides Poly(ethylene glycol) Polystyrene Poly(norbornene) Polyacrylamide Polyaniline Poly(N-vinyl-2-pyrrolidone) Polypyrrole Poly(4-vinylpyridine) Ionic Polymers Organometallic Polymers Functionalized Porous Organic Polymers Miscellaneous Polymers Summary and Outlook COUPLING REACTIONS IN IONIC LIQUIDS Introduction Metal Complexes Metal Salts and Metal on Solid Support Metal Nanoparticles Summary and Outlook CROSS-COUPLING REACTIONS IN AQUEOUS MEDIA Introduction Cross-Coupling of Organic Halides to Form C--C Bonds in Aqueous Media Carbon - Heteroatom Coupling Reactions C--H Activation in Aqueous Media Conclusion and Future Prospects MICROWAVE-ASSISTED SYNTHESIS IN C--C AND CARBON - HETEROATOM COUPLING REACTIONS Introduction C--C Bond Formation C--X Bond Formation Conclusions CATALYST RECYCLING IN PALLADIUM-CATALYZED CARBON - CARBON COUPLING REACTIONS Introduction General Issues of Catalyst Recycling Catalyst Systems Providing High, Consistent Yields in Recycling Catalysts Affording the Highest Cumulative TON Values in Recycling Studies Summary Evaluation Future Outlook NATURE OF THE TRUE CATALYTIC SPECIES IN CARBON - CARBON COUPLING REACTIONS WITH HETEROGENEOUS PALLADIUM PRECATALYSTS Introduction Heck Reactions Suzuki Reactions Sonogashira Reactions Concluding Remarks COUPLING REACTIONS IN CONTINUOUS-FLOW SYSTEMS Introduction Coupling Reactions in Flow Palladium Catalysts for Flow Systems Continuous-Flow Technologies for Cross-Coupling Summary and Outlook PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS - INDUSTRIAL APPLICATIONS Introduction Suzuki - Miyaura Reactions Heck - Mizoroki Reactions Sonogashira - Hagihara Reactions Carbonylations Cyanations Negishi Coupling Novel Pd-Catalyzed C--C Cross-Coupling Reaction Buchwald - Hartwig Aminations Pd-Catalyzed C--S Bond Formation Summary and Outlook