Critical factors influencing the structures and properties of metal-organic frameworks
Critical factors influencing the structures and properties of metal-organic frameworks
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影响金属有机骨架结构和性能的关键因素
DOI：
10.1039/c4ce02150a
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发表时间：
2015
期刊：
影响因子：
3.1
通讯作者：
Zheng Hegen
中科院分区：
文献类型：
--
作者：
Shen Kang;Zhang Mingdao;Zheng Hegen
金属有机骨架(MOF)是一类结构奇特、用途广泛的重要化合物。但到目前为止，有针对性地合成具有所需框架的MOF仍然是一个挑战。为了理解MOF的性质并设计新的框架，有必要从根本上理解如何使MOF的设计和合成合理化。这一重点审查将概述我们和其他小组在这一专题方面的最新进展，并概述影响MOF结构的不同因素。这些例子说明了目前在有机配体和SBU的设计、配位组装和实验条件方面的一些趋势。
Metal–organic frameworks (MOFs) have emerged as an important family of compounds that have fascinating structures and diverse applications. But until now, targeted synthesis of MOFs with desired frameworks is still a challenge. In order to appreciate the properties and to design new frameworks, it is necessary to understand how to rationalize the design and synthesis of MOFs from a fundamental perspective. This highlight review will outline the recent advances in this topic from both our and other groups and provide an overview of the different factors influencing the structures of MOFs. These examples illustrate some of the present trends concerning the design of organic ligands and SBUs, coordination assemblies, and experimental conditions.