Gold- and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP pincer ligand.

Gold- and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP pincer ligand.
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DOI:
10.1002/anie.201200848
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发表时间:
2012-05
期刊:
影响因子:
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通讯作者:
Carolin Tschersich;C. Limberg;S. Roggan;C. Herwig;N. Ernsting;S. Kovalenko;S. Mebs
Carolin Tschersich;C. Limberg;S. Roggan;C. Herwig;N. Ernsting;S. Kovalenko;S. Mebs
中科院分区:
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文献类型:
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作者:
Carolin Tschersich;C. Limberg;S. Roggan;C. Herwig;N. Ernsting;S. Kovalenko;S. Mebs

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贵金属遇到重量级:钳形配体将铋与金和铂结合在一起,因此建立了亲金属相互作用。根据DFT计算,这些相互作用包含主导金属→铋贡献。
Noble metals meet a heavyweight: A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal→bismuth contributions.