Gold- and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP pincer ligand.
Gold- and platinum-bismuth donor-acceptor interactions supported by an ambiphilic PBiP pincer ligand.
复制标题
DOI:
10.1002/anie.201200848
复制
发表时间:
2012-05
影响因子:
--
通讯作者:
Carolin Tschersich;C. Limberg;S. Roggan;C. Herwig;N. Ernsting;S. Kovalenko;S. Mebs
中科院分区:
文献类型:
--
作者:
Carolin Tschersich;C. Limberg;S. Roggan;C. Herwig;N. Ernsting;S. Kovalenko;S. Mebs
Noble metals meet a heavyweight: A pincer ligand brings together bismuth with gold and platinum, so that metallophilic interactions are established. According to DFT calculations, these interactions contain dominant metal→bismuth contributions.