Synthesis of hierarchical Fe2O3/SnO2 hollow heterostructures and their improved photocatalytic properties

Synthesis of hierarchical Fe2O3/SnO2 hollow heterostructures and their improved photocatalytic properties
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多级Fe2O3/SnO2空心异质结构的合成及其改进的光催化性能

DOI:
10.1016/j.matchemphys.2013.09.004
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发表时间:
2013-12
影响因子:
4.6
通讯作者:
Fan, Hai Ming
Fan, Hai Ming
中科院分区:
材料科学3区
文献类型:
--
作者:
Mi, Yu;Cao, Ya Hong;Liu, Xiao Li;Yi, Jia Bao;Tan, Hui Ru;Ma, Pei;Hao, Hong;Zhang, Xin;Fan, Hai Ming

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In the present study, hierarchical α-Fe 2 O 3/SnO 2 hollow heterostructures were successfully synthesized by a template growth method. The crystal structure, morphology, composition and surface area of obtained heterostructures were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and BET surface area analysis. The results reveal that [001]-directed SnO 2 nanorods grow on the side surface of the [001]-directed α-Fe 2 O 3 hollow nanotubes/nanorings, forming (110) α-Fe 2 O 3//(101) SnO 2 and (100) α-Fe 2 O 3//(001) SnO 2 interfaces. These heterostructures can be further converted into magnetic γ-Fe 2 O 3/SnO 2 heterostructure without any significant change in morphology. These α-Fe 2 O 3/SnO 2 hollow heterostructures exhibit much higher photocatalytic activities for degradation of methylene blue in comparison with that of pure α-Fe 2 O 3 nanotubes/nanorings in the wide spectral region from UV to visible due to both larger surface area and improved electron–hole separation efficiency in the interface of heterostructure.
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