Simultaneous construction of polymer backbone and side chains by terpolymerization. Synthesis of polyethers with functional side chains from dialdehydes, alkylene bis(trimethylsilyl) ethers, and trimethylsilyl nucleophiles
Simultaneous construction of polymer backbone and side chains by terpolymerization. Synthesis of polyethers with functional side chains from dialdehydes, alkylene bis(trimethylsilyl) ethers, and trimethylsilyl nucleophiles
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DOI：
10.1021/ma9510101
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发表时间：
1996
期刊：
影响因子：
5.5
通讯作者：
T. Yokozawa;K. Takenoya
中科院分区：
文献类型：
--
作者：
T. Yokozawa;K. Takenoya
聚醚[CHR-R '-CHRO-R-O] n（R= CH 2 CH=CH 2，CN; R ′ = Ph，PhOCOCH 2 CH 2 COOPh; R=（CH 2）2，（CH 2）4，CHMeCHMe，CMe 2 CMe 2，以高氯酸三苯甲基酯为催化剂，二醛CHOR'CHO与亚烷基双（三甲基甲硅烷基）醚Me 3SiOROSiMe 3和三甲基甲硅烷基亲核试剂Me 3SiR
Polyethers [CHR-R'-CHRO-R-O] n (R= CH 2 CH=CH 2 , CN; R'= Ph, PhOCOCH 2 CH 2 COOPh; R= (CH 2 ) 2 , (CH 2 ) 4 , CHMeCHMe, CMe 2 CMe 2 , C 6 H 10 ) have been prepared by trityl perchlorate-catalyzed reductive polycondensation of dialdehydes CHOR'CHO with alkylene bis(trimethylsilyl) ethers Me 3 SiOROSiMe 3 and trimethylsilyl nucleophiles Me 3 SiR