Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers
Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers
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DOI：
10.1039/c2cc31048a
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Real, Jose A.
中科院分区：
文献类型：
--
作者：
Munoz Lara, Francisco J.;Gaspar, Ana B.;Real, Jose A.
在三维自旋交叉多孔配位聚合物{[Fe(吡嗪)[M(CN)(4)]}(M=Pd，Pt)中引入硫脲客体分子，使其在室温附近呈现出约60K宽的空前大的热滞回线。
Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)(4)]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.