Paradigms shift when solvent-less fluids come into play.
Paradigms shift when solvent-less fluids come into play.
复制标题
当无溶剂流体发挥作用时，范式就会发生变化。
DOI：
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发表时间：
2015
期刊：
影响因子：
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通讯作者：
S. S. Babu
中科院分区：
文献类型：
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作者：
S. S. Babu
无溶剂有机流体是一类新型功能性软材料。这里可用的流体基质使其与溶剂辅助系统具有同等的竞争力。在这个视角中，强调了有机流体挑战既定和公认的范式的方式。一般来说，光异构化、能量/电子转移、光子上转换和可逆双氧结合等基本性质是由溶剂和/或溶剂极性、氧的存在等控制的。这里，无溶剂流体通过在纯净、无溶剂和环境条件下实现它来挑战范例。这一新阶段的研究创造了许多潜在的功能材料，与溶剂辅助系统相比，它们的工作效果更好、更高效。因此，这个相对较新的研究课题和结果需要特别关注。在这里，我们讨论一些代表性的例子，以指出它们在运作中面临的挑战。
Solvent-less organic fluids are a new class of functional soft materials. Here the available fluid matrix makes it equally competitive with the solvent assisted systems. In this Perspective, the ways in which organic fluids challenge the established and accepted paradigms is highlighted. In general, fundamental properties such as photoisomerization, energy/electron transfer, photon upconversion and reversible dioxygen binding are controlled by solvents and/or solvent polarity, the presence of oxygen etc. Here solvent-less fluids challenge the paradigms by realizing it under neat, solvent-less and ambient conditions. This new phase of research has created many potential functional materials, which work better and more efficiently compared to the solvent assisted systems. Hence this relatively new research topic and the results need special attention. Here we discuss a few representative examples to point out the challenges offered in their functioning.
影响因子：
8.4
作者：
Brogan, Alex P. S.;Siligardi, Giuliano;Mann, Stephen
通讯作者：
Mann, Stephen
影响因子：
15
作者：
Marsico, Filippo;Turshatov, Andrey;Wurm, Frederik R.
通讯作者：
Wurm, Frederik R.