Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones
Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones
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DOI：
10.1021/acscatal.5b01299
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发表时间：
2015-09-01
期刊：
影响因子：
12.9
通讯作者：
Soos, Tibor
中科院分区：
文献类型：
--
作者：
Gyoemoere, Adam;Bakos, Maria;Soos, Tibor
在本文中，我们报告了一个工作台稳定的硼烷的挫折刘易斯对催化还原醛，酮和烯酮的发展。通过对刘易斯酸组分的结构和电子参数的精细调整以及对刘易斯碱的选择，首次提供了一种耐湿的FLP催化剂。相关的NMR和DFT研究支持了这种FLP催化剂的独特行为，并深入了解了所得FLP催化剂的催化活性。
In this paper, we report on the development of a bench-stable borane for frustrated Lewis pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of structural and electronic parameters of Lewis acid component and the choice of Lewis base provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic activity of the resulting FLP catalyst.