Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds.
Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds.
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本文报道了中性硅基钌配合物与酮和醛的反应，以及它们的碱性中间体的分离，其中羰基化合物的α-H提取或氢化硅烷化反应取决于底物的取代基。
Reactions of a neutral silyleneruthenium complex with ketones and aldehydes, and isolation of their agostic intermediates are reported, where an alpha-H abstraction or hydrosilylation of the carbonyl compounds occurs depending on the substituents of the substrates.